国产含杂环的芳香族聚酰胺纤维的热分解动力学  

Kinetics of Thermal Decomposition of Domestic Heterocyclic Aromatic Polyamide Fibers

作　　者：杨锐[1] 陈蕾[1] 于俊荣[1] 王彦[1] 诸静[1] 胡祖明[1] 

机构地区：[1]东华大学纤维材料改性国家重点实验室,上海201620

出　　处：《东华大学学报（自然科学版）》2014年第4期379-384,共6页Journal of Donghua University(Natural Science)

基　　金：国家重点基础研究发展计划(973)资助项目(2011CB606103);国家"八六三"高技术研究发展计划资助项目(2012AA03A212);中央高校基本科研业务费专项资金资助项目(11D10625)

摘　　要：通过热重分析,考察并比较了国产含杂环的芳香族聚酰胺纤维F-12纤维和芳纶Ⅲ的热分解过程及动力学.在不同升温速率(5,10,15,20℃/min)下,获得热重和微分热重曲线,并采用Kissinger,Friedman,Flynn-Wall-Ozawa 3种热分析方法,对F-12纤维和芳纶Ⅲ的热分解动力学行为进行了对比研究,得到了两者的热分解反应动力学方程.研究结果表明,F-12纤维的热稳定性稍优于芳纶Ⅲ.The processes of thermal decomposition and kinetics analysis of F-12 fiber and aramid fiber Ⅲ were studied and compared by thermo-gravimetric （TG） and differential thermo-gravimetric （DTG） analysis.The thermal behaviors and kinetic parameters of F-12 fiber and aramid fiber Ⅲ at different heating rates （5,10,15,20 ℃/min） were investigated based on Kissinger,Friedman and Flynn-Wall-Ozawa methods by TG-DTG,both of the kinetic equations of thermal decomposition were obtained.The research results show that the thermal stability of F-12 fiber is better than that of aramid fiber Ⅲ.

关 键 词：F-12纤维 芳纶Ⅲ 热分解 热重分析 非等温动力学 

分 类 号：TQ340.7[化学工程—化纤工业]