The Scaling Law in the Fine-Structure Splitting of ls2np States for the Lithium Isoelectronic Sequence  

作　　者：蔡娟 于伟威 张楠 

机构地区：[1]School of Physics and Electronic Technology, Liaoning Normal University, Dalian 116029

出　　处：《Chinese Physics Letters》2014年第9期44-47,共4页中国物理快报（英文版）

基　　金：Supported by the National Natural Science Foundation of China under Grant No 11074102, and the Young Scientists Fund of the National Natural Science Foundation of China under Grant No 11204118.

摘　　要：The ＇full-core plus correlation＇ （FCPC） and the ＇minimizing the expectation value of the Hamiltonian＇ methods are extended to calculate the fine-structure splitting of ls2np （n = 2-9） states for the lithium-like systems from Z = 21 to 30. The leading order relativistic effect is included by using first-order perturbation theory. The higher- order relativistic and the quantum-electrodynamics contributions to the fine-structure splitting are investigated under a hydrogenic approximation with effective nuclear charges, Our results are compared with other theoretical calculations and experimental results. It is shown that the FCPC method is also effective to obtain the ionic structure for high nuclear ions of lithium-like systems. By fitting our theoretical results, the scaling law of the fine-structure splitting of the lithium isoelectronie sequence behaves like a quartie function of the screened nuclear charge Z＊.The ＇full-core plus correlation＇ （FCPC） and the ＇minimizing the expectation value of the Hamiltonian＇ methods are extended to calculate the fine-structure splitting of ls2np （n = 2-9） states for the lithium-like systems from Z = 21 to 30. The leading order relativistic effect is included by using first-order perturbation theory. The higher- order relativistic and the quantum-electrodynamics contributions to the fine-structure splitting are investigated under a hydrogenic approximation with effective nuclear charges, Our results are compared with other theoretical calculations and experimental results. It is shown that the FCPC method is also effective to obtain the ionic structure for high nuclear ions of lithium-like systems. By fitting our theoretical results, the scaling law of the fine-structure splitting of the lithium isoelectronie sequence behaves like a quartie function of the screened nuclear charge Z＊.

分 类 号：O562.1[理学—原子与分子物理] O641.1[理学—物理]