PWO橡胶复合材料制备及γ射线辐射防护性能研究  

Preparation and study of γ-ray protective properties of lead tungstate rubber composite

作　　者：王莉[1] 周元林[1] 李迎军[1] 

机构地区：[1]西南科技大学四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地,四川绵阳621010

出　　处：《功能材料》2014年第18期18120-18124,共5页Journal of Functional Materials

基　　金：国家自然科学基金委员会-中国工程物理研究院联合基金资助项目(11176026);四川省非金属复合与功能材料国家重点实验室开放基金资助项目(13zxfk07)

摘　　要：通过不同表面活性剂制备出两种不同形貌的PbWO4晶体,并作为功能填充料添加到天然胶乳当中,得到具有良好力学性能及γ射线防护性能的PbWO4橡胶复合材料。采用XRD、SEM、荧光(PL)、电子万能试验机、NaI(TI)探测仪等方法对晶体的结构和性质及复合橡胶的力学性能、γ射线辐射防护特性作了分析和表征。结果表明,不同形貌的PbWO4晶体在橡胶基质中分散良好,光致发光性质越好的PbWO4晶体对γ射线的屏蔽率越好,最高可达20.79%(填量为30%),且粒径越小在胶乳中分散越好的PbWO4晶体,有助于提高γ射线的屏蔽率,力学性能明显高于未添加PbWO4晶体的纯天然胶乳。In this paper,lead tungstate(PbWO4 )crystals with two different morphologies have been synthesized via a direct precipitation method by using various surfactants.All of crystals will lead to good mechanical prop-erties andγ-ray protective performance of PbWO4 rubber composite when they were added into natural rubber latex as functional units.By using XRD,SEM,fluorescence(PL),electronic universal testing machine and NaI (TI)detectors,the structure and property of microcrystals have been analyzed,the mechanical properties andγ-ray protective performance of composite rubber have been characterized.The results indicated that PbWO4 microcrystals were well dispersed in natural rubber latex.PbWO4 crystals with better photoluminescence prop-erties will present higherγ-ray shielding rates which reaches the highest value of 20.79% (filler content 30%). And smaller size of PbWO4 crystals which dispersed well in natural rubber latex will contribute to improvingγ-ray shielding rate.The mechanical strength was significantly higher than those pure natural latex without adding PbWO4 crystals.

关 键 词：钨酸铅 橡胶复合材料 复合改性 γ射线防护 

分 类 号：TQ317.3[化学工程—高聚物工业]