笼型十缩水甘油基倍半硅氧烷的制备与表征  

Synthesis and Characterization of Cage Decaglycidyl Polyhedral Oligomeric Sisesquioxanes

作　　者：孔国强[1] 李莹[1] 孙晓冬[1] 尹磊[1] 魏化震[1] 李居影 安振河[1] 毕卫东[1] 

机构地区：[1]中国兵器工业集团第五三研究所,济南250031

出　　处：《工程塑料应用》2014年第9期34-36,共3页Engineering Plastics Application

摘　　要：以3-(2,3-环氧丙氧)丙基三甲氧基硅烷(KH–560)为单体,在异丙醇为溶剂、四甲基氢氧化铵(TMAH)为催化剂的体系中一步水解缩合制备出笼型缩水甘油基倍半硅氧烷(G–POSS)。采用傅立叶变换红外光谱、核磁共振波谱及基质辅助激光解吸飞行时间质谱等手段对产物进行了分析和表征。结果表明,成功地合成了高纯度的笼型十缩水甘油基倍半硅氧烷(T10)。Cage glydidyl polyhedral oligomeric silsesquioxanes（G-POSS） was prepared by one-step hydrolytic condensation from 3-（2,3-epoxypropoxy） propytrimethoxysilane（KH-560） in the system of isopropyl alcohol and tetramethylammonium hydroxide （TMAH）. G-POSS was characterized using FTIR,1H-NMR and MALDI-TOF-MS. The results show that highly purified cage decaglycidyl polyhedral oligomeric silsesquioxanes is successfully prepared.

关 键 词：笼型十缩水甘油基倍半硅氧烷 一步水解缩合 分析 

分 类 号：TQ264.1[化学工程—有机化工]