双酚A分子印迹材料的制备及其性能评价  

Performance Evaluation Based on Molecularly Imprinted Materials of Bisphenol

作　　者：苏立强[1] 周磊[1] 翟明翚[1] 郭晓丽[1] 陈超男[1] 

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006

出　　处：《化学试剂》2014年第9期835-838,共4页Chemical Reagents

基　　金：黑龙江省教育厅基金资助项目(12531757);精细化工黑龙江省高校重点实验室基金资助项目(JX201208)

摘　　要：以双酚A为模板分子,2-乙烯吡啶为功能单体,乙二醇二甲基丙烯酸酯为交联剂,V(甲苯)∶V(液体石蜡)=3∶2混合溶液为溶剂,采用沉淀聚合法制备对双酚A具有亲和选择性的印迹微球。通过静态吸附、Scatchard分析及Langmuir吸附模型对印迹材料的吸附特性进行分析,并且运用选择性吸附对印迹材料进行评价。结果表明:印迹材料存在一类性质相同结合位点,吸附过程属于单分子层吸附,对目标分子双酚A具有较好的特异选择性。The molecularly imprinted materials based on precipitation polymerization were prepared with bisphenol A as template molecule, 2-vinylpyridine as functional monomer, ethylene glycol dimethacrylate as cross-linker, V（ toluene）： V（llquid paraffin） = 3：2 mixed solution as solvent. The adsorption capacity was investigated with static adsorption, scatchard model analysis and Langmuir model analysis. The adsorption capacity of molecularly imprinted materials was evaluated by selective adsorption. The experimental results demonstrated that there was one certain type of binding sites existing in the molecularly imprinted materials and its adsorption process was single molecule layer adsorption. Selective adsorption text illustrated that as-prepared MIP possessed favorable specific selectivity.

关 键 词：分子印迹材料 双酚A 沉淀聚合 吸附特性 

分 类 号：O652.6[理学—分析化学]