无溶剂法合成聚苯基硫代膦酸乙二醇酯的研究  

Study on the Synthesis of Polyethylene Glycol Phenyl Phosphorothioate under Solvent-free Condition

作　　者：韩虹[1] 王彦林[2] 张艳丽[2] 杨小琴[2] 

机构地区：[1]新乡学院化学与化工学院,河南新乡453003 [2]苏州科技学院化学与生物工程学院,江苏苏州215009

出　　处：《化学世界》2014年第9期517-519,523,共4页Chemical World

基　　金：苏州市应用基础研究计划项目(SYJG0928)

摘　　要：在无溶剂条件下,以苯基硫代膦酰二氯、乙二醇为原料,合成一种新型大分子含硫有机膦阻燃剂。其最适宜的工艺条件为:苯基硫代膦酰二氯与乙二醇的摩尔比=1∶1,在140℃下常压反应3h,然后再减压反应7h,产率为88%。用红外、核磁、热分析,元素分析等对产物进行了表征,并对其阻燃性能进行了研究。A novel polymeric sulfur-containig organophosphorus flame retardant polyethylene glycol phenylhosphorothioate was synthesized from phenyhhiophosphonic dichloride and glycol under solvent-free condition. The optimal reaction conditions were as follows： n（phenyhhiophosphonicdichloride） ： n（glycol）= 1 ：1, the reaction was carried out under 140℃for 3 h and then at the same temperature under decompressionfor 7 h. The yield was 88%. The chemical structure of the product was characterized by IR, 1 H NMR andelemental analysis. Its thermall degradation behavior and flammability properties were investigated by TG-DTA and oxygen index analyzer.

关 键 词：苯基硫代膦酰二氯 含硫有机膦阻燃剂 无溶剂法 合成 

分 类 号：TQ314.24[化学工程—高聚物工业]