芳基重氮盐参与的偶联反应研究进展  

Research Progress on Cross-Coupling with Aryl Diazonium Salts

作　　者：宣赏赐 王晓丹[1] 王建伟[1] 赵保丽[1] 程凯[1] 齐陈泽[1] 

机构地区：[1]绍兴文理学院浙江省精细化学品传统工艺替代技术研究重点实验室,绍兴312000

出　　处：《有机化学》2014年第9期1743-1758,共16页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21402123);浙江省自然科学基金(No.LQ14B020001);浙江省科技厅(No.2012R10014-15);浙江省教育厅(No.Y201328443);绍兴市科技计划(No.2013014017)资助项目~~

摘　　要：芳基重氮盐由于其价廉易得、反应活性高等特点作为芳基化试剂广泛应用于偶联反应中,近年来在有机合成中越来越受到化学家们的重视.综述了2006年以来的芳基重氮盐参与的偶联反应的研究情况,结合本课题组的工作,重点探讨芳基重氮盐在新的碳碳键构筑方式、天然产物骨架的构建、非均相催化领域的延伸以及绿色合成等方面的新应用和新进展.Aryl diazonium salts have been widely used in cross-coupling reaction due to its easily available and highly reactivity as arylation reagents, which have drawn more and more attention by chemists in organic synthesis in recent years. The research progress since 2006 on cross-coupling with aryl diazonium salts combined with our work is reviewed, focusing on new applications and new progress of aryl diazonium salts in new method to build carbon-carbon bond, with construction of the natural product skeleton, in the field of heterogeneous catalysis and other aspects of green synthesis.

关 键 词：芳基重氮盐 偶联反应 碳碳键的构筑 绿色合成 

分 类 号：O621.25[理学—有机化学]