Fluorinated 1,8-naphthalimides:Synthesis,solid structure and properties  

作　　者：Jie Huang Di Wu Hao-Jie Ge Sheng-Hua Liu Jun Yin 

机构地区：[1]Key Laboratory of Pesticide and Chemical Biology,Ministry of Education,College of Chemistry,Central China Normal University

出　　处：《Chinese Chemical Letters》2014年第10期1399-1402,共4页中国化学快报（英文版）

基　　金：support from National Natural Science Foundation of China(Nos.21072070,21272088);the Program for Academic Leader in Wuhan Municipality(No. 201271130441);supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education,the Natural Science Foundation of Hubei Province(No.2013CFB207);Excellent doctorial dissertationcultivation grant from Central China Normal University(No. 2013YBYB60)

摘　　要：Three fluorinated 1,8-napthalimides were synthesized from acenaphthene.Their structures were characterized by NMR and EI-MS analyses.The structures of compounds 1b and 1c were also confirmed by X-ray diffraction analysis,which showed that they possessed different packing models.Their optoelectronic properties were investigated.The results indicated that all of the naphthalimides possess good solubility and low LUMO energy level,which make them good solution processing candidates in n-type semiconductor.Three fluorinated 1,8-napthalimides were synthesized from acenaphthene.Their structures were characterized by NMR and EI-MS analyses.The structures of compounds 1b and 1c were also confirmed by X-ray diffraction analysis,which showed that they possessed different packing models.Their optoelectronic properties were investigated.The results indicated that all of the naphthalimides possess good solubility and low LUMO energy level,which make them good solution processing candidates in n-type semiconductor.

关 键 词：Napthalimide n-Type semiconductor Optoelectronic properties 

分 类 号：O621.3[理学—有机化学]