国内催化合成草酸二丁酯的进展  

Progress on Catalytic Synthesis of Dibutyl Oxalate in Domestic

作　　者：俞善信[1] 文瑞明[2] 

机构地区：[1]湖南师范大学化学化工学院,长沙410081 [2]湖南城市学院化学与环境工程系,益阳413000

出　　处：《塑料助剂》2014年第5期11-15,共5页Plastics Additives

基　　金：湖南省教育厅科研基金资助项目(01C022;05C774)

摘　　要：评述了对甲苯磺酸,对甲苯磺酸铜,氨基磺酸,强酸性阳离子交换树脂,六水三氯化铁,固载三氯化铝,五水四氯化锡,硫酸铜,七水硫酸锌,氧化钐,一水硫酸氢钠,硫酸氢钾,固体超强酸,杂多酸和维生素C等催化剂催化合成草酸二丁酯的合成方法。认为固载对甲苯磺酸,对甲苯磺酸铜,氨基磺酸,强酸性阳离子交换树脂,活性碳固载四氯化锡,氧化钐,一水硫酸氢钠,硫酸氢钾,固体超强酸,杂多酸和维生素C是合成草酸二丁酯的良好催化剂。微波辐射是有机合成的良好方法。The catalytic synthesis of dibutyl oxalate with p-toluene sulfonic acid,copper p-toluene sulfonate,amino sulfonic acid,strong-acid positive ion exchange resin,ferric chloride hexahydrate,supper aluminium chloride,stannic chloride pentahydrate,copper sulfate,zine sulfate sevenhydrate,Sm2O3,sodium bisulfate monohydrate,potassium bisulfate,solid super acid,heteropoly acid and vitamin C were reviewed.The solid supported p-toluene sulfonic acid,copper p-toluene sulfonate,amino sulfonic acid,strong-acid positive ion exchang resin,supported stannic chloride,Sm2O3,sodium bisulfate monohydrate,potassium bisulfate,solid super acid,heteropoly acid and vitamin C are more suitable for catalytic synthesis of dibutyl oxalate.Microwave irradiation are a good method of organic synthesis.

关 键 词：草酸二丁酯 合成 催化剂 

分 类 号：TQ225.24[化学工程—有机化工]