PA66/GF/PPO共混材料的动态流变性能  被引量:8

Dynamical Rheological Behavior of PA66/GF/PPO Blends

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作  者:赵朋[1] 颜浩[1] 马诗雯 王标兵[1] 

机构地区:[1]常州大学材料科学与工程学院,江苏常州213100

出  处:《工程塑料应用》2014年第10期64-68,共5页Engineering Plastics Application

摘  要:通过熔融共混法在双螺杆挤出机上制备了尼龙(PA)66/玻璃纤维(GF)/聚苯醚(PPO)三元共混材料,采用旋转流变仪研究了共混材料的流变行为。结果表明,PA66及共混材料均为假塑性流体,呈现剪切变稀现象;GF和PPO的加入增大了共混材料的储能模量和损耗模量;用Han方法表明复合材料没有发生相分离;经动态时间扫描发现,共混材料的储能模量随着时间的增加而增大。PA66/GF/PPO blends were prepared by melt blending on twin-screw extruder,and the dynamical rheological behaviors of the blends were studied by using rotational rheometer. The experimental results show that PA66/GF/PPO blends were pseudo plastic fluid,and specimens exhibite shear-thinning behavior. The storage modulus,loss modulus and the complex viscosity of PA66/GF/PPO blends were increased after the incorporation of GF and PPO. The phase separation is not occured for composite as demonstrated by the analysis of Han curve. Time scanning shows that the storage modulus of the composite increases with the increasing of time.

关 键 词:尼龙66 聚苯醚 共混材料 流变性能 储能模量 损耗模量 

分 类 号:TQ342.11[化学工程—化纤工业]

 

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