FeOx对Mn-Ti复合氧化物催化剂催化燃烧氯苯性能的影响  

Effect of FeO_x on the performance of Mn-Ti complex oxide catalysts for the catalytic combustion of chlorobenzene

作　　者：易全瑞[1] 赵培[1] 刘善堂[1] 

机构地区：[1]武汉工程大学化学与环境工程学院绿色化工过程教育部重点实验室,武汉430073

出　　处：《功能材料》2014年第22期22041-22045,22050,共6页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(21471120);湖北省科技厅资助项目(2012IHA002);湖北省教育厅资助项目(T201306)

摘　　要：采用溶胶-凝胶法制备了一系列不同Fe含量的MnOx-TiO2催化剂,使用氢气程序升温还原(H2-TPR)、X射线光电子能谱(XPS)、比表面积测定(BET)和X射线衍射(XRD)等技术对其进行了表征,考察了该类催化剂催化燃烧氯苯(CB)的活性和稳定性。催化活性测试结果表明,Fe的添加改善了MnOxTiO2催化剂的活性,同时显著提高了该催化剂的稳定性。表征结果表明,适量FeOx的添加能明显提高催化剂的比表面积,促进了各活性组分的分散,提高了催化剂表面活性氧物种和晶格氧的数量,使催化剂表面的氧化能力大幅度提高,从而提高了FeOx-MnOxTiO2催化剂的活性和稳定性。In this study,a series of MnOx-TiO2 and FeOx-MnOx-TiO2 catalysts were prepared using a sol-gel method and were investigated for the catalytic combustion of chlorobenzene (CB).The result revealed that FeOx-MnOx-TiO2 catalysts exhibited a relatively higher catalytic activity than that of MnOx-TiO2 catalysts. Moreover,a remarkably higher stability was detected for the FeOx-MnOx-TiO2 samples compared with Mn-Ti catalysts,indicating that the stability of MnOx-TiO2 samples could be enhanced by the addition of Fe.The syn-thetized catalysts were characterized using H2 temperature-programmed reduction(H2-TPR),X-ray photoelec-tron spectroscopy(XPS),brunauer-emmett-teller(BET)surface measurement,and X-ray diffraction(XRD). Characterization of the catalysts revealed that the appropriate addition of FeOx to the MnOx-TiO2 catalysts would increase the specific surface area of the catalysts,which promotes the dispersion of Mn species over the TiO2 supports.In addition,the introduction of Mn also increases the amount of active oxygen species on the catalyst surface and lattice oxygen,which would in turn significantly enhance the oxidation abilities of catalysts. All of above reasons account for the higher catalytic activity and stabilities of FeOx-MnOx-TiO2 catalysts.

关 键 词：溶胶-凝胶 FeOx-MnOx-TiO2催化剂 氯苯 催化氧化 

分 类 号：O643.36[理学—物理化学] TQ426.6[理学—化学]