双氧水氧化环己烯催化合成己二酸研究进展  

Research progress of synthesis of adipic acid through catalytic oxidation of cyclohexene by hydrogen peroxide

作　　者：金邻豫[1] 刘姗姗[1] 孙昆仑[1] 郝志华[1] 何建英[1] 

机构地区：[1]河南大学化学化工学院,河南开封475004

出　　处：《化学研究》2014年第6期648-652,共5页Chemical Research

基　　金：河南省科技厅科技发展计划项目(112102210008)

摘　　要：评述了近年来以环己烯为底物,双氧水为氧源,分别采用钨酸盐、钨酸、杂多酸及杂多酸盐、功能化分子筛和负载离子液体等为催化剂催化合成己二酸的研究进展.A review is given about the research progress of the synthesis of adipic acid with cyclohexene as the substrate and hydrogen peroxide as the clean oxidant as well as tungstate, tungstic acid, heteropoly acid and its salt, functional molecular sieve and immobilized ionic liquid as the catalysts.

关 键 词：双氧水 环己烯 催化氧化 己二酸 合成 研究进展 

分 类 号：TQ225.1[化学工程—有机化工]