轴向取代金属酞菁的制备及Li/SOCl_2电池催化性能研究  

Preparation of Axially Substituted Metal Phthalocyanine and Catalytic Performance Study of Li/SOCl_2 Battery

作　　者：李莹莹[1] 赵建社[2] 

机构地区：[1]陇东学院化学化工学院,甘肃庆阳745000 [2]西北大学化学与材料科学学院,陕西西安710069

出　　处：《陇东学院学报》2014年第5期28-31,共4页Journal of Longdong University

摘　　要：以邻苯二腈和金属盐为原料,分别采用微波法和液相法合成了两个系列13种轴向取代金属酞菁配合物,并对所合成的金属酞菁进行了锂/亚硫酰氯(Li/SOCl2)电池催化性能测试,结果表明:与空白实验相比较,催化剂的加入可以明显提高Li/SOCl2电池的放电电压和放电时间。其中,铜酞菁放电电量提高81.96%,苯并异吲哚啉轴向取代硅酞菁放电量提高112.62%。Two series complexes of axially substituted metal phthalocyanines were synthesized by microwave and liquid phase method by using o-benzene diacetonitrile and metal salts as starting material , and the catalytic activity to lithium/thionyl chloride batteries were investigated .The results reveal that the addition of catalyst can obviously increase the discharge voltage and time of Li /SOCl2 battery compared with the blank experiment , in which the relative energy of benzo Isoindoline axially substituted silicon phthalocyanine increased by 112 .62%, relative energy of copper phthalocyanine increased by 81.96%.

关 键 词：轴向取代酞菁 LI/SOCL2电池 催化活性 

分 类 号：O61[理学—无机化学]