Burning characteristics of microcellular combustible objects  

作　　者：Wei-tao YANG Yu-xiang LI San-jiu YING 

机构地区：[1]School of Chemical Engineering,Nanjing University of Science and Technology

出　　处：《Defence Technology（防务技术）》2014年第2期106-110,共5页Defence Technology

基　　金：funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions

摘　　要：Microcellular combustible objects for application of combustible case,caseless ammunition or combustible detonator-holding tubes are fabricated through one-step foaming process,in which supercritical CO_2 is used as foaming agent.The formulations consist of inert polymer binder and ultra fine RDX.For the inner porous structures of microcellular combustible objects,the cell sizes present a unimodal or bimodal distribution by adjusting the foaming conditions.Closed bomb test is to investigate the influence of both porous structure style and RDX content on burning behavior.The sample with bimodal distribution of cell sizes burns faster than that with unimodal distribution,and the concentration of RDX can influence the burning characteristics in a positive manner.In addition,the translation of laminar burning to convective burning is determined by burning rate versus pressure curves of samples at two different loading densities,and the resulting transition pressure is 30 MPa.Moreover,the samples with bigger sample size present higher burning rate,resulting in providing deeper convective depth.Dynamic vivacity of samples is also studied.The results show that the vivacity increases with RDX content and varies with inner structure.Microcellular combustible objects for application of combustible case, caseless ammunition or combustible detonator-holding tubes are fabricated through one-step foaming process, in which supercritical CO2 is used as foaming agent. The formulations consist of inert polymer binder and ultra fine RDX. For the inner porous structures of microcellular combustible objects, the cell sizes present a unimodal or bimodal distribution by adjusting the foaming conditions. Closed bomb test is to investigate the influence of both porous structure style and RDX content on burning behavior. The sample with bimodal distribution of cell sizes burns faster than that with unimodal distribution, and the concentration of RDX can influence the burning characteristics in a positive manner. In addition, the translation of laminar burning to convective burning is determined by burning rate versus pressure curves of samples at two different loading densities, and the resulting transition pressure is 30 MPa. Moreover, the samples with bigger sample size present higher burning rate, resulting in providing deeper convective depth. Dynamic vivacity of samples is also studied. The results show that the vivacity increases with RDX content and varies with inner structure.

关 键 词：燃烧性能 可燃物 超临界二氧化碳 发泡过程 多孔结构 双峰分布 单峰分布 压力曲线 

分 类 号：TK16[动力工程及工程热物理—热能工程]