Targeted synthesis of novel porous aromatic frameworks with selective separation of CO_2/CH_4and CO_2/N_2  

作　　者：Wei Wang Ye Yuan Fu-Xing Sun Guang-Shan Zhu 

机构地区：[1]State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University

出　　处：《Chinese Chemical Letters》2014年第11期1407-1410,共4页中国化学快报（英文版）

基　　金：support of the National Natural Science Foundation of China(No.0831002);Major International (Regional) Joint Research Project(No.21120102034)

摘　　要：Novel porous aromatic frameworks（PAF-53 and PAF-54） have been obtained by the polymerization of amino compound（p-phenylenediamine and melamine） and cyanuric chloride. They display a certain amount of CO2 adsorption capacity and highly selective separation of CO2/CH4 and CO2/N2 as 18.1 and83 by Henry Law respectively. They may be applied as ideal adsorbents to separate and capture CO2.Novel porous aromatic frameworks（PAF-53 and PAF-54） have been obtained by the polymerization of amino compound（p-phenylenediamine and melamine） and cyanuric chloride. They display a certain amount of CO2 adsorption capacity and highly selective separation of CO2/CH4 and CO2/N2 as 18.1 and83 by Henry Law respectively. They may be applied as ideal adsorbents to separate and capture CO2.

关 键 词：Porous aromatic framework Cyanuric chloride Selective separation CO 2 adsorption 

分 类 号：TQ424.3[化学工程]