响应面法优化乌桕梓油多元醇合成工艺  

Optimization of the synthesis process of sapium sebiferum kernel oil polyol

作　　者：马飞[1] 吴桂英[1] 闫云君[1] 

机构地区：[1]华中科技大学生命科学与技术学院,湖北武汉430074

出　　处：《应用化工》2014年第10期1758-1761,1774,共5页Applied Chemical Industry

基　　金：国家"863"课题(2011AA02A204)

摘　　要：以环氧乌桕梓油、甲醇、水为原料,以氟硼酸为催化剂,对环氧乌桕梓油进行醇解开环合成乌桕梓油多元醇工艺进行了研究。结果表明,最佳工艺参数为:催化剂用量0.3%,甲醇环氧基摩尔比12.9∶1,醇水摩尔比4.3∶1,转速200 r/min,反应时间73 min,反应温度73℃。在此条件下,乌桕梓油多元醇羟值为212.67 mgKOH/g,转化率达96.5%。Using epoxidized sapium sebiferum kernel oil,methanol,and water as raw materials,and fluobo-rie aeid as eatalyst,an investigation on the synthesis proeess of the sapium sebiferum kernel oil polyol via aleoholysis of epoxidized sapium sebiferum kernel oil was eondueted. Based on the single faetor experiment and response surfaee method,the optimized eonditions were eatalyst 0. 3%,molar ratio of methanol to ep-oxy group 12. 9 ：1,molar ratio of methanol to water 4. 3 ：1,stirring speed 200 r/min,reaetion time 73 min,and reaetion temperature 73 ℃. Under the optimal eonditions,the hydroxyl value of the sapium sbife-rum kernel oil polyol was 212. 67 mgKOH/g,the eonversion rate attained 96. 5%.

关 键 词：乌桕梓油多元醇 合成 响应面 

分 类 号：TQ314[化学工程—高聚物工业]