铁催化硅氢加成反应研究进展  

Progress in Hydrosilylation Catalyzed with Iron Catalyst

作　　者：徐大鹏[1] 肖文军[1] 彭家建[1] 厉嘉云[1] 白赢[1] 

机构地区：[1]杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州311121

出　　处：《有机化学》2014年第11期2195-2201,共7页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21303035);浙江省自然科学基金(No.LY14B030007)资助项目~~

摘　　要：铁催化剂应用于催化硅氢加成反应,具有原料丰富度高、低成本、低毒性等优点,在近几年得到迅速发展.总结了铁催化剂在碳-碳双键、碳-氧双键及其他杂原子不饱和双键硅氢加成反应中的应用,并展望了铁催化剂在有机硅化学领域的应用前景.Iron catalysts gained great development in hydrosilylation of various types of unsaturated double bond compounds due to their advantages of high raw material abundance, low cost, low toxicity, etc. The applications of iron catalysts are summarized in the hydrosilylation of carbon-carbon double bond, carbon-oxygen double bond and other heteroatomic double bond. The application prospect of iron catalysts in the field of organic silicon chemistry is looked forward.

关 键 词：铁配合物 硅氢加成 碳-碳双键 杂原子双键 进展 

分 类 号：O643.32[理学—物理化学]