有机-无机复合物[Zn(C_(10)H_8N_2)_3][HPMo_(12)O_(40)(VO)_2]的合成、晶体结构及性能研究  

Synthesis,Structure and Properties of a Novel Organic-inorganic Hybrid Complex [Zn(C_(10)H_8N_2)_3][HPMo_(12)O_(40)(VO)_2]

作　　者：叶燕珠[1] 谢茹胜 张贤金[1] 吴新建[1] 

机构地区：[1]福建教育学院理科研修部,福建福州350001 [2]福建生物工程职业技术学院,福建福州350002

出　　处：《福建师范大学学报（自然科学版）》2014年第6期51-55,共5页Journal of Fujian Normal University：Natural Science Edition

基　　金：福建省教育厅资助项目(JA14348)

摘　　要：通过水热法合成了一种新型的有机-无机复合物[Zn(C10H8N2)3][HPMo12O40(VO)2],用X-射线单晶衍射技术及红外光谱对其结构进行了表征,并探讨了该复合物在仲辛醇选择性氧化制己酸中的催化活性.实验结果表明,该复合物是由1个金属有机配离子[Zn(C10H8N2)3]2+和1个多金属氧酸阴离子[HPMo12O40(VO)2]2-构成的,二者之间通过静电引力结合,该复合物对仲辛醇氧化制己酸具有较高的催化活性.A novel organic-inorganic hybrid complex, [ Zn（ C,0HsN2 ） 3 ] [ HPMo12040 （VO） 2 ] has been synthesized hydrothermally and structurally characterized by IR and X-ray crystallography. X-ray structure analyses revealed that the title complex was constructed from [ Zn （ C10 Hs N2 ）3 ] 2 - metal-organic complex cation and [ HPMo12 040 （VO） 2 ] 2 - cluster anion with electrostatic attraction. The catalytic activity of the title complex was tested in the oxidation of 2-Octanol to hexanoic acid. The results showed that the title complex exhibited good catalytic activity for oxidation of 2-Octanol to hexanoic acid.

关 键 词：有机-无机复合物 多金属氧酸盐 水热合成 催化活性 

分 类 号：O614[理学—无机化学]