新型金配合物——NH_4[Au(MA)_2]·H_2O的合成、性质及镀金应用  

Synthesis of Novel Gold Complex Aurous Ammonium Thioglycolate as well as Its Physicochemical Properties and Application in Gold Electroplating

作　　者：冯能清[1] 李德良[1] 刘玺[1] 盛国军[1] 张闯 

机构地区：[1]中南林业科技大学材料科学与工程学院,湖南长沙410004 [2]长沙铂鲨环保设备有限公司,湖南长沙410007

出　　处：《材料保护》2014年第12期1-3,6,共3页Materials Protection

基　　金：国家自然科学基金资助项目(20976201);湖南省自然科学基金资助项目(07JJ6156)资助

摘　　要：为了减少和避免镀金过程中剧毒物质氰、腈的使用,以巯基乙酸为配体合成了一种新型亚金配合物巯基乙酸亚金铵;采用试金法和元素分析仪分析了其成分,用红外光谱、紫外光谱、热失重分析和导电性测量等研究了其基本理化性质,并将其用于电镀金。结果表明:合成产物的分子式为NH4[Au(MA)2]·H2O,以巯基乙酸的巯基和金配位为成键特征,在200℃之前热稳定性较好;以NH4[Au(MA)2]·H2O为金源,通过四因素三水平的正交试验获得了最佳镀金参数:电流密度200~300 A/m2,光亮剂十二烷基磺酸钠浓度5~8 m L/L,温度35~50℃,金浓度15~25 g/L;所得电镀金层表面光滑,颗粒尺寸在0.5~1.0μm内为单质金,均匀性好,镀层色泽、结合力优良。A novel aurous ammonium thioglycolate was synthesized with thioglycolic acid as the ligand so as to replace highly toxic cyanogen and nitrite used for gold electroplating.The composition of as- synthesized product was determined by assaying method and elemental analysis method.The physicochemical properties of the product were investigated by infrared spectrometry,ultraviolet spectrometry,differential thermal analysis,and conductivity measurement.Moreover,as-synthesized product was used for gold electroplating,and the optimal electroplating parameters were determined by orthogonal tests covering three factors.Results indicated that the as-synthesized product had a formula of NH_4[Au(MA)_2]H_2O.The product was characterized by the covalenl bonding between Au(Ⅰ) and mercapla group,and it exhibited good thermal stability below 200℃.Moreover,the optimal electroplating parameters with NH_4[Au(MA)_2]·H_2O as the gold source were suggested as current density of 200 ~ 300A/m^2,brightener concentration of 5—8 mL/L,temperature of35-50℃,and Au(Ⅰ) concentration of 15-25g/L.Resultant Au coating consisted of metallic Au grains with a size of 0.5-1.0 μm and was smooth and uniform,while it exhibited desired luster and good adhesion to the substrate.

关 键 词：巯基乙酸亚金铵 合成 结构 理化性质 电镀金 应用 

分 类 号：O641.4[理学—物理化学] TQ153.18[理学—化学]