Multi-walled carbon nanotubes as novel promoter of catalysts for certain hydrogenation and dehydrogenation reactions  

作　　者：Guodong Lin Xuelian Liang Zhiming Liu Jianrong Xie Binghui Chen Hongbin Zhang 

机构地区：[1]State Key Laboratory of Physical Chemistry of Solid Surfaces [2]National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters [3]College of Chemistry and Chemical Engineering, Xiamen University

出　　处：《Science China Chemistry》2015年第1期47-59,共13页中国科学（化学英文版）

基　　金：supported by the National Basic Research Program of China(2011CBA00508);the National Natural Science Foundation of China(20923004);the Program for Changjiang Scholars and Innovative Research Team in University(IRT1036)

摘　　要：From the chemical catalysis viewpoint,the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive,in addition to their nanosize channels,sp2-C constructed surfaces,and high thermal/electrical conductivity.This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions,e.g.,hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2,mainly based on recent work carried out in our laboratory.From the chemical catalysis viewpoint, the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive, in addition to their nanosize channels, sp2-C constructed surfaces, and high thermal/electrical conductivity. This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions, e.g., hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2 mainly based on recent work carried out in our laboratory.

关 键 词：multi-walled carbon nanotubes catalysts supported or promoted by CNTs hydrogenation-conversion of syngas toalcohols decomposition or steam-reforming of methanol to yield H2 

分 类 号：TQ426[化学工程] TQ223.121