乙醇胺改性硅胶吸附剂对模拟沼气中CH_4/CO_2的分离性能  

Separation peformance of CH_4/CO_2 simulated in biogas for monoethanolamine modified SiO_2

作　　者：李文哲[1] 高海云[1] 杨海燕[2] 丁清华[1] 

机构地区：[1]东北农业大学工程学院,哈尔滨150030 [2]东北农业大学理学院,哈尔滨150030

出　　处：《农业工程学报》2014年第22期267-272,共6页Transactions of the Chinese Society of Agricultural Engineering

基　　金："十二五"国家科技支撑计划资助项目(2011BAD15B00)

摘　　要：沼气的主要成分是CH4和CO2,有效地去除沼气中的CO2是确保沼气成为优质燃气的必要条件。吸附法是去除沼气中CO2的有效方法,研制性能优良的吸附剂是吸附法研究的核心问题。该文以FNG-II型硅胶为载体,乙醇胺(ethanolamine,MEA)为改性剂,制备了MEA改性硅胶吸附剂,表示为FS-MEA(FNG-II Silica-ethanolamine)。用X射线衍射、N2物理吸附脱附法、热重-差热、红外光谱等手段对吸附材料的结构、比表面积、孔结构、改性后结构变化等进行了分析。通过动态吸附分离试验,考察了FS-MEA对CH4/CO2的分离性能。结果表明:改性方法可将MEA附着在载体内孔表面,制得的FS-MEA可有效地分离CH4/CO2,但经过2次使用再生后,FS-MEA对CH4/CO2的分离性能有所下降,因此必须提高乙醇胺改性硅胶吸附剂的再生性能,才有可能使其应用于沼气提纯。The major components of biogas by anaerobic digestion are CH4 and CO2, so it is necessary to selectively separate CO2 from CH4 in order to improve heating value of biogas. Adsorption technology has been considered a competitive method for separating gases because of its relatively simple equipment and low energy consumption. It is well known that developing an excellent adsorbent is the key issue for adsorption separation. In the present work, MEA-modified FNG-II silica adsorbent was prepared by a conventional wet impregnation technique and the new adsorbent was named as FS-MEA. Silica was selected as the substrate and monoethanolamine （MEA） was modified at the outer surface of substrate. In order to coat the silica surface with MEA uniformly, MEA was dissolved in methanol in advance. The new adsorbent was characterized by powder X-ray diffraction （XRD）, nitrogen adsorption/desorption, thermogravimetric analysis （TGA） and Fourier transform infrared spectroscopy （FTIR） to determine pore pacing, pore volume, pore diameter, the organic loading on the substrate and amines. The results of XRD and nitrogen adsorption/desorption for the adsorbents showed that FNG-II silica contains a large amount of disordered mesopores. After 30 wt.%MEA loading, the mesoporous structures were preserved, but the specific surface area and pore volume decreased, which provided strong evidence that MEA could be attached to the inner pore surfaces of the silica. This result is in agreement with FTIR analysis. The TGA curves showed a unique significant mass loss on FNG-II silica under atmospheric pressure from 29℃to 870℃and the weight loss was derived from desorption of moisture. However for cases of FS-MEA, two major mass loss steps were observed in the same conditions. The first step in the range of 29℃to 170℃was attributed to desorption of moisture and CO2 that absorbed in MEA modified on the substrate. The second mass loss step occurred when the temperature was higher than 210℃, which were ascribed to the volati

关 键 词：沼气 硅胶 吸附剂 提纯 乙醇胺 

分 类 号：S216.4[农业科学—农业机械化工程]