Copolymerization and Properties of Multicomponent Crosslinked Hydrogels  

作　　者：Zheng-bai Zhao Shuang-shuang An Hai-jiao Xie 姜勇 

机构地区：[1]School of Chemistry and Chemical Engineering, Southeast University

出　　处：《Chinese Journal of Polymer Science》2015年第1期173-183,共11页高分子科学（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(No.21174029);the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry

摘　　要：A series of multicomponent hydrogels were prepared by the copolymerization of hydrophobic silicon-containing monomer 3-bis（trimethylsilyloxy） methylsilylpropyl glycerol methacrylate（Si MA） with the solvent-responsive monomers 2-hydroxyethyl methacrylate（HEMA） and N-vinyl pyrrolidone（NVP） and thermosensitive monomer N,N-dimethyl acrylamide（DMA）. 2-Hydroxy-2-methyl phenyl acetone（D-1173） was chosen as UV initiator and five different dienes/triene monomers were selected as crosslinking agent in order to select the best crosslinker. The ethanol extraction experiments as well as the FTIR, DSC and TG results showed that the copolymerization was effective. The optical, permeability, and mechanical analysis results demonstrated that the obtained hydrogels were highly transparent with good oxygen permeability and mechanical properties. And the impact of crosslinker on the mechanical properties of the hydrogels was also discussed in detail. The basic results demonstrated that the obtained hydrogels had good stimuli-responsive effects to both p H value and solvent.A series of multicomponent hydrogels were prepared by the copolymerization of hydrophobic silicon-containing monomer 3-bis（trimethylsilyloxy） methylsilylpropyl glycerol methacrylate（Si MA） with the solvent-responsive monomers 2-hydroxyethyl methacrylate（HEMA） and N-vinyl pyrrolidone（NVP） and thermosensitive monomer N,N-dimethyl acrylamide（DMA）. 2-Hydroxy-2-methyl phenyl acetone（D-1173） was chosen as UV initiator and five different dienes/triene monomers were selected as crosslinking agent in order to select the best crosslinker. The ethanol extraction experiments as well as the FTIR, DSC and TG results showed that the copolymerization was effective. The optical, permeability, and mechanical analysis results demonstrated that the obtained hydrogels were highly transparent with good oxygen permeability and mechanical properties. And the impact of crosslinker on the mechanical properties of the hydrogels was also discussed in detail. The basic results demonstrated that the obtained hydrogels had good stimuli-responsive effects to both p H value and solvent.

关 键 词：Multicomponent hydrogel Silicon-containing monomer Hydrophilic monomer Crosslinker Stimuli-responsive. 

分 类 号：O648.17[理学—物理化学]