BODIPY-苯酚类化合物的阴离子识别性能  

Anion recognition properties based on BODIPY-phenol receptors

作　　者：吕永军[1] 

机构地区：[1]四川理工学院材料与化学工程学院,四川自贡643000

出　　处：《西北师范大学学报（自然科学版）》2015年第1期61-64,共4页Journal of Northwest Normal University(Natural Science)

基　　金：四川理工学院人才引进项目(2012RC02)

摘　　要：合成了两种氟硼二吡咯亚甲基(BODIPY)-苯酚衍生物1和2,用紫外-可见吸收光谱研究了其阴离子识别性能.结果表明,主体1和2对F-,AcO-和H2PO-4有选择性识别作用,吸收光谱分别红移了186和133nm,溶液由粉红色变成淡绿色.主客体分子间发生脱质子化作用,且其亲合作用力顺序为:F->AcO->H2PO-4和1>2,这主要归因于阴离子碱性和主体2中特丁基的位阻效应和给电子共轭效应.Two BODIPY‐phenol derivatives 1 and 2 are designed and synthesized , and their anion recognition properties are investigated by UV‐Vis spectra technology . The results show that receptors 1 and 2 exhibit the selectivity for F^- ,AcO^- and H2 PO4 , w hich results in 186 and 133 nm red shift in absorption spectra , respectively , and the color changes from pink to light green . Receptors can interact with three anions by deprotonation with the affinity order ：F^- 〉AcO^- 〉 H2PO4^- and 1〉2 ,which can be ascribed to the basicity of special anions and the steric hindrance effect and electron‐donating conjugative effect of tert‐butyl group .

关 键 词：BODIPY 苯酚 阴离子识别 脱质子化 特丁基 

分 类 号：O641.3[理学—物理化学] O657.32[理学—化学]