溶剂热法可控合成纳米氯化亚铜  

Controllable synthesis of nano-cuprous chloride by solvothermal method

作　　者：李永生[1] 韩腾[1] 谢光勇[1] 张爱清[1] 

机构地区：[1]中南民族大学化学与材料科学学院催化材料科学国家民委-教育部重点实验室,湖北武汉430074

出　　处：《应用化工》2014年第12期2135-2136,2143,共3页Applied Chemical Industry

基　　金：国家自然科学基金(21172269);武汉市应用基础研究计划(2014010101010017);精细化工国家重点实验室开放基金(KF1207)

摘　　要：以氯化铜为铜源，甲醇、乙醇、异丙醇等为溶剂和还原剂，采用溶剂热法制备纳米氯化亚铜，探讨了温度、时间、还原剂等条件对所得氯化亚铜的形貌、粒径大小、物相组成的影响。结果表明，以乙醇、异丙醇为溶剂，在120~180℃反应24~48 h，CuCl纳米颗粒可在2~50 nm范围内有效调控。A solvothermal method has been developed to prepare cuprous chloride nanoparticles by reduc-ing copper chloride with methanol,ethanol and isopropanol as reducing agents and solvents,and the influ-ences of different reaction conditions such as temperatures,time and reducing agents upon the morpholo-gy,particle size and phase composition of the cuprous chloride were studied. The result showed that with ethanol and isopropanol as solvent,react 24~48 h at 120~180℃. The size of CuCl nanoparticles can be controlled in the range of 2~50 nm effectively.

关 键 词：氯化亚铜 纳米粒子 溶剂热法 

分 类 号：TQ131.21[化学工程—无机化工]