Convection and Phase-Separation Behavior of Binary Mixture under Microwave Irradiation  

作　　者：Yusuke Asakuma Koh Yutaka 

机构地区：[1]Mechanical and System Engineering, University of Hyogo, Himeji 671-2280, Japan

出　　处：《Journal of Chemistry and Chemical Engineering》2014年第9期859-864,共6页化学与化工（英文版）

摘　　要：When the temperature of a thin layer of a solution is vertically controlled, Rayleigh-Bemard convection is observed. When a binary isobutyric acid aqueous solution is used as the binary mixture, phase separation is simultaneously induced at the approximate critical solution temperature. In this study, these behaviors of phase separation and convection were observed under microwave irradiation. When the microwave power was higher, coalescence of fine droplets after the initial phase separation was accelerated and the coalescence size decreased. However, the solution became more unsteady because of smaller interfacial tension or greater heat generated by the radiation. Finally, in cases of higher microwave power, a steady convection pattern could not exist for a prolonged period because the water-rich phase was more active toward microwave irradiation, and the vertical temperature gradient became disordered.

关 键 词：MICROWAVE phase separation Rayleigh-Bernard convection. 

分 类 号：O632.31[理学—高分子化学] TB612[理学—化学]