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作 者:李军[1] 朱建新[1] 李庆彪[1] 黄际伟[1] 陶熏[1]
出 处:《化工新型材料》2015年第1期15-16,36,共3页New Chemical Materials
基 金:国家自然科学基金项目(20672023);广州市科技计划项目(2011Y1-00010);广东省科技计划项目(2012B050100010)
摘 要:高能量密度的电极活性材料是提高电芯能量密度的关键。提高锂离子电池能量密度的途径主要包括开发高比容量正负极材料和高放电电压平台正极材料。本研究综述了几种典型的具有高能量密度锂离子电池正、负极材料的最新研究进展,包括多电子反应、富锂、聚阴离子和镍锰酸锂正极材料以及硬碳、硅基和锡基负极材料,介绍了各种材料的特点和电化学性能,重点阐述了制备这些材料的典型方法和进展,并展望了高能量密度锂离子电池的发展方向和应用前景。Electrode active materials with high energy density is the key to improve the energy density of battery. The main methods to improve the energy density of lithium-ion battery, including exploiting the high capacity and high dis- charge voltage anode materials or negative materials. The several kinds of typical anode and negative materials with high energy density in recent research progressions were summarized, including anode materials such as multi-electrons reaction material, lithium rich material, the polyanion compounds and LiNi0.5 Mn1.5O4 ; negative materials such as hard carbon, silicon based negative materials and tin based negative materials. The characteristics and the electrochemical behaviors of various materials were introduced, emphasis was placed on the discussion of the typical methods of preparations and recent progress. Finally, the development trend and application prospects of lithium-ion battery with the high energy density were forecasted.
关 键 词:锂离子电池 高能量密度 动力电池 储能电池 电极材料
分 类 号:TM912[电气工程—电力电子与电力传动]
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