海因环氧树脂的制备及其应用  

Preparation and application of hydantoin epoxy resin

作　　者：唐功文[1,2] 黄鑫[2] 

机构地区：[1]中国海洋大学化学化工学院,山东青岛266100 [2]国家海洋局天津海水淡化与综合利用研究所,天津300192

出　　处：《功能材料》2015年第5期5019-5025,5032,共8页Journal of Functional Materials

基　　金：国家科技支撑计划资助项目(2011BAD33B03);中央级公益性科研院所基本科研业务费专项基金资助项目(2012-T6)

摘　　要：海因环氧树脂是由海因或其衍生物经缩水甘油化而得到的含有乙内酰脲杂环的新型特种环氧树脂,保持了环氧树脂的原有应用性能,同时乙内酰脲的杂环结构又赋予其优异的电绝缘性、耐热性、耐候性和耐磨性等特性,具有广阔的应用前景。总结了1,3-二缩水甘油基海因、缩水甘油醚类海因环氧树脂和大分子海因环氧树脂3种类型海因环氧树脂的制备方法,简要介绍了近年来关于海因环氧树脂的基本性能研究,并对其在电子封装材料、覆铜板的基板材料、绝缘材料、材料抗菌剂及其它领域的应用进行了阐述,最后探讨了海因环氧树脂在工业重防腐领域中的应用潜力。Hydantoin epoxy resin is a new type of special epoxy resin,which was glycidylated hydantoin and its derivatives.It maintains the performance of ordinary epoxy resin.More over,heterocyclic structure of hydantoin makes hydantoin epoxy resin with good electrical isolation,heat resistance,weather resistance and abrasion performance.In this review,the preparation of 1,3-glycidyl hydantoin,glycidyloxy hydantoin epoxy resin and hydantoin epoxy resin with high molecular weight were reviewed.The current research status about the performances of hydantoin epoxy resin was reviewed.The application of hydantoin epoxy resin in the fields of electronic packaging materials,substrate material of copper clad laminate,insulation material,antibacterial agent and so on were described.The development trend of hydantoin epoxy resin was further predicted.

关 键 词：海因 海因环氧树脂 缩水甘油化 

分 类 号：TQ630.4[化学工程—精细化工] TQ323.5