水溶液常温条件下制备咪唑啉硫酮类杂环化合物  

Preparation of Imidazolidinethione Heterocyclic Compound in Water at Room Temperature

作　　者：李甜甜[1] 马宁[1] 孙菲菲[1] 

机构地区：[1]天津大学理学院,天津300072

出　　处：《化学与生物工程》2014年第12期31-34,共4页Chemistry & Bioengineering

摘　　要：在水相中以乙二胺和二硫化碳常温反应制备2-咪唑啉硫酮,对制备条件进行了优化,探讨了不同底物对反应的影响,并通过熔点、核磁共振氢谱、红外光谱、质谱对产物进行了表征。结果表明,1,2-环己二胺、邻苯二胺、邻氨基苯酚、1,6-己二胺、盐酸萘乙二胺等底物均能适用于本反应而得到预期的产物。Using ethylenediamine and carbon disulfide as raw materials,2-imidazolinethione was prepared in water at room temperature.The effects of preparation conditions and different substrates on reaction were investigated.The products were characterized by melting point,1 HNMR,IR and MS.Results showed that,1,2-cyclohexanediamine,o-phenylenediamine,o-aminophenol,1,6-hexanediamine and naphthyl ethylenediamine dihydrochloride were applicable to the method to give the desired products.

关 键 词：杂环化合物 咪唑啉硫酮 二胺类化合物 水相反应 

分 类 号：O626.23[理学—有机化学]