壳聚糖及其衍生物负载过渡金属催化剂在有机反应中的应用进展  

Applications of Chitosan and Its Derivatives Supported Transitional Metal Catalysts in Organic Reactions

作　　者：王硕[1] 周宏勇[1] 宋沙沙[1] 王家喜[1] 

机构地区：[1]河北工业大学化工学院,天津300130

出　　处：《有机化学》2015年第1期85-91,共7页Chinese Journal of Organic Chemistry

基　　金：河北省自然科学基金(No.B2011202087)资助项目~~

摘　　要：壳聚糖因其与金属化合物的良好络合性能成为金属催化剂的优良载体,壳聚糖及其衍生物负载金属及金属络合物的催化性能研究近年来引起人们的广泛关注.以反应类型为主线,对这类催化剂在不对称催化、烯丙基取代、偶联反应、加成反应、氧化反应、还原反应等各类有机反应中的应用进行了综述.Due to its good coordination ability to the metal compounds, chitosan and its derivatives can be used as a kind of good catalysts carrier. Recently, the catalytic properties of chitosan and its derivatives supported metal catalyst have been attracted more attentions. Based on the kind of reactions, the applications of chitosan and its derivatives supported metal catalysts in the catalytic asymmetric reaction, allylic substitution, coupling, addition, oxidation, reduction and some other reactions are reviewed.

关 键 词：壳聚糖 壳聚糖衍生物 过渡金属 催化反应 不对称反应 

分 类 号：O621.251[理学—有机化学]