硫含量对中碳非调质钢中硫化物及组织的影响  

Effect of sulfur content on sulfide inclusions and microstructure in medium carbon non-quenched and tempered steel

作　　者：李梦龙[1,2] 王福明[1,2] 孟庆勇[1,2] 陶素芬[1,2] 李长荣[3] 

机构地区：[1]北京科技大学钢铁冶金新技术国家重点实验室,北京100083 [2]北京科技大学冶金与生态工程学院,北京100083 [3]北京科技大学材料科学与工程学院,北京100083

出　　处：《工程科学学报》2015年第2期168-174,共7页Chinese Journal of Engineering

基　　金：国家自然科学基金资助项目(51174020;51374018);国家高技术研究发展计划资助项目(2013AA031601);中央高校基本科研业务费专项资金资助项目(FRF-SD-12-010A)

摘　　要：利用真空感应炉冶炼了不同硫含量的中碳非调质钢，研究了S含量对非调质钢中硫化物形态分布及显微组织的影响．结果表明：在0．025％～0．065％范围内，随S质量分数的增加，非调质钢中硫化物的数量增多，偏聚分布现象加重；晶内铁素体比例随之升高，组织得到细化．通过热力学计算及相图信息研究了硫化物的类型转变．S含量增加时第Ⅲ类MnS在凝固末期以离异共晶形式较早析出，剩余液相中的S在凝固结束时以共晶形式析出为第Ⅱ类MnS．单独MnS以及MnS-V（C，N）复合硫化物均可作为晶内铁素体的有效形核核心，促进铁素体的生成．Medium carbon non-quenched and tempered steels with different S contents were smelted with a vacuum induction fur- nace. Several experiments were conducted to study the effect of S content on the morphology of sulfides and microstructure in the steels. The results show that with the increase of S content from 0. 025 wt% to 0. 065 wt% , the number of sulfide inclusions increases, and the aggregation of sulfide inclusions is promoted, while the microstructure becomes finer due to the increasing area ratio of in- tragranular ferrite. Thermodynamic calculations and phase diagram information were employed to explain the transition of MnS from type Ⅱ to type m. The angular type Ⅲ MnS is resulted from divorced eutectic reaction before the solidification completes, and the rod-like type Ⅱ MnS is derived from normal eutectic reaction at the end of the solidification process. Both MnS and MnS- V （ C, N） complex inclusions are found to act as effective nucleation sites to improve the formation of intragranular idiomorphic ferrite.

关 键 词：中碳钢 夹杂物 硫化物 铁素体 相图 

分 类 号：TF701.3[冶金工程—钢铁冶金]