含氟丙烯酸酯单体及其改性氨基硅油的合成方法  

Method for Synthesis of Fluorinated Acrylate Monomer and Its Modified Amino Silicone Oil

作　　者：陈剑君[1] 周佳丽[1] 吴雪妹[1] 陶晓红[1] 朱成红 吴浩杰[1] 徐杨军 吕亮[1] 

机构地区：[1]衢州学院化学与材料工程学院,浙江衢州324000 [2]衢州新诺高分子材料有限公司,浙江衢州324002

出　　处：《皮革与化工》2015年第1期23-25,33,共4页Leather And Chemicals

基　　金：浙江省重点技术创新项目(2014183);国家级大学生创新创业训练计划项目(201311488005);浙江省大学生科技创新活动计划(2014R427011);衢州市科技计划项目(20111047;20111051;2013Y11);衢州学院科研基金重点项目(KZZ1101)

摘　　要：氨基硅油是有机硅油中的重要品种,氟原子的引入是提高氨基硅油性能的有效手段。本文简述了含氟丙烯酸酯单体的合成、氨基硅油的接枝改性方法。通过Michael加成接枝氟单体所得最终改性氨基硅油乳液具有良好的防水、防油、耐黄变及稳定性能。Amino silicone oil is an important variety of organic silicone oil. The introduction of fluorine atom is an effective method to improve the performance of amino silicone oil. In this paper, the synthesis of fluorinated acrylate monomer and graft modification of amino silicone oil were described.The grafting of fluorine monomer modified amino silicone oil emulsion by Michael addition. And Modified amino silicone oil emulsion has a good waterproof, oil proof performance, yellowing resistance property and emulsion stability.

关 键 词：氨基硅油 丙烯酸酯 氟代 接枝 

分 类 号：TQ264.1[化学工程—有机化工]