SBA-15固载Salen金属配合物催化剂的研究  

Study on the Salen Metal Complexes Catalysts Immobilized by SBA-15

作　　者：王丹[1] 刘素芹[1] 

机构地区：[1]天津长芦海晶集团有限公司,天津300450

出　　处：《盐业与化工》2014年第12期34-37,共4页Jounral of Salt and Chemical Industry

摘　　要：文章主要介绍了以SBA-15分子筛为载体合成负载的Salen Co(Ⅲ)配合物的一种全新方法,研究了该配合物作为催化剂用于环氧氯丙烷的水解动力学拆分反应时其循环使用次数,以及反应条件对水解拆分e.e%值的影响。One fully new way was introduced that Salen Co（ Ⅲ ） complexes were synthesized with SBA - 15 molecular sieve as a carrier. The recycling reaction times of this kind of complexes were studied when they were applied in the hydrolytic kinetic resolution of epichlorohydrin as the catalyst. It was also discussed that the condition of this kind of reaction influences e. e % and the value of hydrolytic kinetic resolution.

关 键 词：SBA-15 手性SALEN Co(Ⅲ)配合物 水解动力学拆分 

分 类 号：TQ426.64[化学工程]