Bi_2O_3在软质PVC制品中的阻燃应用研究  

Effect of Bi_2O_3 on Flame Retardancy of Flexible PVC

作　　者：王旭[1] 崔葵馨[1] 李希鹏[1] 谢大鹏[2] 袁节平[2] 金胜明[1] 

机构地区：[1]中南大学资源加工与生物工程学院,湖南长沙410083 [2]湖南柿竹园有色金属有限责任公司,湖南郴州423037

出　　处：《合成材料老化与应用》2015年第1期5-8,101,共5页Synthetic Materials Aging and Application

摘　　要：将不同晶型的Bi2O3阻燃剂添加到软质PVC材料中,采用极限氧指数和烟密度评价Bi2O3对软质PVC的阻燃性能,并与常用的氧化锑(Sb2O3)和钼酸铵协同阻燃剂进行阻燃抑烟比较,结果表明:5%的β-Bi2O3阻燃剂添加至软质PVC时氧指数达35.5,烟密度为75%;而6%氧化锑与3%钼酸铵协同添加后软质PVC的氧指数达到35,烟密度为85.5%。SEM和TG/DSC表征Bi2O3在软质PVC中的分散和热分解特性,结果表明:β-Bi2O3的在PVC树脂中分散性优于α-Bi2O3,Bi2O3的加入使PVC前期热释放速率降低,后期分解释放小分子速度和数量均有所降低,增加了成碳率,从而提高PVC的氧指数和降低烟密度。In this paper,the use of Bi2O3 with different crystal forms as flame retardant additives was investigated and compared to the formulations with Sb2O3 and ammonium molybdate in flexible PVC. The retarding effect was evaluated by its limiting oxygen index and smoke density. Results showed that the oxygen index of PVC were 35. 5and 35,while the smoke density were 75% and 85. 5% after adding 5% β-Bi2O3 and 6% Sb2O3＋ 3% ammonium molybdate,respectively. SEM revealed that the dispersibility of β-Bi2O3 was better than that of α-Bi2O3 in PVC,and TG / DSC curves indicated that addition of Bi2O3 resulted in the decrease of thermal-release rate of igniting PVC in early stage,the decomposition rate and amount of small molecules in later stage that enhanced carbonation effect,thereby increased oxygen index and decreased PVC smoke density.

关 键 词：BI2O3 阻燃 抑烟 软质PVC 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]