功能化硅胶负载钯的制备以及在Heck反应中的应用  

Functionalized Mesoporous Silica-supported Palladium Catalyst for Heck Coupling Reactions

作　　者：孙文晶[1] 

机构地区：[1]广东医学院中美肿瘤研究所,广东东莞523808

出　　处：《广东化工》2015年第3期35-36,43,共3页Guangdong Chemical Industry

基　　金：国家自然科学基金青年基金(21406039)

摘　　要：硅胶表面存在大量的硅羟基官能团(Si-OH),通过对其表面进行有机或无机改性,再固载金属Pd配合物,可合成一种应用于Heck催化领域的新型催化剂。文章通过对二氧化硅表面进行氨基化改性后负载钯,并进一步使用等离子特殊场处理,制备出了两种二氧化硅负载钯催化剂。催化剂应用于Heck反应中,考察了这两种催化剂的催化性能和稳定性。The functional group Si-OH on the surface of the Si O2 can react with a specific molecular. So the surface property of the Si O2 could be modified though organic or inorganic reaction. The modified Si O2 can be used as the carrier to new catalysts. In this paper the amino group was introduced on the surface of Si O2 via using the silica gel coupling agent. Furthermore, the catalysts were treated by Plasma. Those catalysts were applied in Heck synthesis, the stability catalytic performances were investigated.

关 键 词：HECK反应 钯 硅胶载体的功能化 等离子体 

分 类 号：TQ[化学工程]