对称的双二茂铁基甲酰胺的合成、表征及电化学性质  

Synthesis,Characterization and Electrochemical Properties of Symmetric Diferrocenyl Formamide

作　　者：邓秀琴[1] 葛春华[2] 

机构地区：[1]辽宁石油化工大学顺华能源学院,辽宁抚顺113001 [2]辽宁大学化学院,辽宁沈阳110036

出　　处：《化学试剂》2015年第3期209-211,216,共4页Chemical Reagents

基　　金：辽宁省自然科学基金资助项目(2013020085)

摘　　要：以二茂铁甲酸为主要原料,经卤代和酰胺化两步反应合成了一种标题衍生物——N-4-二茂铁苯基二茂铁甲酰胺。通过红外光谱、核磁共振氢谱和质谱对其结构进行了表征,并用循环伏安法研究了其电化学性质。结果表明,该化合物中两个二茂铁基团之间通过酰胺键迁移电子,从而使两个二茂铁基团可以分别被氧化还原,并且该化合物分子具有良好的氧化还原可逆性。By using ferrocenecarboxylic acid as main raw material,a kind of ferroceneformamide derivative,called N-4-ferrocenyl phenyl ferroceneformamide,was synthesized by halogenation and amidation two-step reactions. The structure was confirmed by IR,1HNMR and mass spectrometry. The electrochemical properties was investigated by cyclic voltammetry. The results show that the two ferrocene groups in the compound transfer the electrons through amide bond,so that the two ferrocenyl groups can be oxidized or reduced respectively,and the molecule has a good oxidation-reduction reversibility.

关 键 词：对称 双二茂铁基甲酰胺 合成 表征 电化学性质 

分 类 号：O614.81[理学—无机化学]