旋光性聚酰胺研究进展  

Progress in Synthesis of Optically Active Polyamide

作　　者：张玲丽[1,2] 付鹏[1] 崔喆[1] 刘民英[1] 赵清香[1] 

机构地区：[1]郑州大学材料科学与工程学院,郑州450052 [2]郑州职业技术学院生物工程系,郑州450121

出　　处：《工程塑料应用》2015年第3期133-136,共4页Engineering Plastics Application

基　　金：国家自然科学基金项目(201443003);863计划项目(2011AA02A204);河南省创新人才计划项目(124200510011)

摘　　要：按化学结构对旋光性聚酰胺进行了分类,包括用非手性单体制备的旋光性酰胺、侧链含手性原子及主链含手性原子的旋光性聚酰胺。对旋光性聚酰胺的合成方法进行了总结,介绍了链增长缩聚法、溶液聚合法和界面缩聚法在合成旋光性聚酰胺方面的应用。The category of optically active polyamide was introduced according to chemical structure, which was constructed by monomers bearing chiral side groups, monomers having chiral atoms in main chain and achiral monomers respectively. The synthesis methods of optically active polyamides were reviewed. Chain-grown condensation polymerization, solution polymerization and interracial polymerization that were used to achieve optically active polyamides were introduced in detail.

关 键 词：聚酰胺 旋光性聚酰胺 螺旋结构 聚合 

分 类 号：O632.6[理学—高分子化学]