多巴胺复合超滤膜的制备及其在海水养殖废水处理中的应用  

Preparation of Composite Ultrafiltration Membrane With Dopamine and Its Application in the Wastewater Treatment in Aquaculture

作　　者：王栋[1] 徐佳[1] 单宝田[1] 宋迪[1] 刘瑞聪[1] 

机构地区：[1]中国海洋大学化学化工学院海洋化学理论与工程技术教育部重点实验室,青岛266100

出　　处：《渔业科学进展》2015年第1期119-123,共5页Progress in Fishery Sciences

基　　金：山东省科技发展计划项目(2012GHY11529;2014GHY115033);山东省优秀中青年科学家科研奖励基金(BS2012HZ016)共同资助

摘　　要：将聚砜基膜浸泡在2 g/L的多巴胺溶液中,在震荡培养箱中涂覆12 h,之后用去离子水震荡清洗24 h得到多巴胺复合超滤聚砜膜。红外光谱分析结果显示,复合膜为多巴胺聚合在聚砜膜表面形成的复合膜,接触角为63°,较基膜减小21°,亲水性显著加强;在0.10 MPa压力下,对海水养殖废水进行分离实验,对海水养殖废水总悬浮物(TSS)、化学需氧量(COD)的去除率分别达到100%、83.3%,具有良好的去除效果。In recent years, the marine aquaculture has been undergoing a rapid development in the quantity and the scale of this industry. The wastewater from marine aquaculture inevitably causes pollution to the adjacent sea water if discharged without proper treatment. In order to meet the criteria of recycling or discharge, currently people have mainly used physical, chemical, and biological methods to remove the suspended solids （SS） and ammonia nitrogen in the wastewater, and to reduce chemical oxygen demand （COD） and biological oxygen demand （BOD）. However these traditional methods have certain shortcomings in processing wastewater generated in marine aquaculture. Compared to the traditional treatment, membrane technology has the advantages such as the convenient operation and management and high efficiency, although it brings in membrane pollution during the application. In this study, we coated polysulfone ultrafiltration membrane with dopamine, and examined the properties and the functional performance of the dopamine composite ultrafiltration polysulfone membrane. The preparation of the composite membrane included coating and cleaning. The polysulfone membrane was first immersed in dopamine solution at the concentration of 2 g/L for 12 hours in a concussion incubator. The coated membrane then underwent vibration cleaning with deionized water for 24 hours. Infrared spectroscopy analysis showed that dopamine polymerization formed on the surface of the polysulfone membrane. The contact angle was 63° which was 21° smaller than the basal membrane. The hydrophilism of the composite membrane was significantly increased compared to the basal membrane. The results of separation experiments with aquaculture wastewater showed that under the pressure of 0.10 MPa the removal rates of TSS and COD were 100% and 83.3% respectively, indicating high-quality wastewater treatment.

关 键 词：多巴胺复合膜 超滤 海水养殖 废水处理 

分 类 号：S967[农业科学—水产养殖]