锌-琥珀酸铵还原体系用于氢化偶氮苯的合成  

The Synthesis of Hydrazobenzene through Zinc- Ammonium Succinate System

作　　者：张高举[1] 孙婷[1] 

机构地区：[1]许昌学院化学化工学院,河南许昌461000

出　　处：《浙江化工》2015年第2期44-46,共3页Zhejiang Chemical Industry

基　　金：河南省教育厅自然科学研究项目(2011A150025)

摘　　要：用锌-琥珀酸铵饱和水溶液组合成还原体系,以偶氮苯作为原料来制备氢化偶氮苯。实验结果表明:偶氮苯与锌粉物质的量之比为1:6.0(偶氮苯1.25 mmol),饱和琥珀酸铵溶液用量为4.0 m L时为最佳反应条件,反应时间大约3 min,平均产率为91.51%。对产品进行熔点测定及红外光谱分析。The synthetic method of hydrazobenzene with azobenzene through Zn-saturated solution of ammonium succinate reduction system was reported. The optimum reaction conditions of Zn-saturated solution of ammonium succinate were that the molar ratio of azobenzene to zinc powder was 1∶6.0（the amount of azobenzene is 1.25 mmol）, the saturated solution of ammonium succinate was 4.0 m L, the reaction time is about 3 min at temperature of 25 ℃, the yield was 91.51%. Melting point measurement and IR spectrum analysis were carried out on the product.

关 键 词：氢化偶氮苯 锌-饱和琥珀酸铵溶液 还原 

分 类 号：O625.65[理学—有机化学]