基于偶氮苯的光开关分子探针与传感芯片研究进展  

Progress of Azobenzene-based Photoswitchable Molecular Probes and Sensory Chips in Chemical and Biological Analysis

作　　者：钦传光[1] 鲁彩霞[1] 欧阳高伟 钦可 张峰[1] 王晓辉[1] 石海通 

机构地区：[1]西北工业大学理学院应用化学系,教育部空间物理与化学重点实验室,陕西省高分子科学与技术重点实验室,西安710129 [2]清华大学理学院化学系,北京100084

出　　处：《分析化学》2015年第3期433-443,共11页Chinese Journal of Analytical Chemistry

基　　金：国家自然科学基金(Nos.20672086;20802057);国家级大学生创新创业训练计划项目(No.201410699074);陕西省自然科学基础研究计划重点项目(No.2012JZ2002);西北工业大学研究生创业种子基金项目(No.Z2014073)资助~~

摘　　要：随着人们对偶氮苯光致异构化反应机制和特性的研究和认识越来越深入透彻,偶氮苯衍生物无论是在理论上还是在实验方面都受到了大量的关注。近年来,偶氮苯衍生物作为光开关响应的功能元件不仅已经用于合成智能聚合物,液晶材料,分子开关和分子机器等,而且正迅速地渗透到化学生物学体系研究和分析的各个方面。因此,本文将着重就基于偶氮苯衍生物功能化的光开关型分子探针与传感芯片及其在化学生物学分析研究方面所取得的最新进展进行总结和综述。引用103篇文献,并对未来的发展前景进行了展望。Azobenzene derivatives have received considerable experimental and theoretical attention,along with more and more the investigation and the knowledge on the characteristics of their photo-induced isomerization. Except for their traditionally well-known uses as dyes or colorants in many industries,in recent years,azobenzene derivatives have been widely used as photoresponsive functional devices utilized not only as smart polymers,liquid crystals,molecular switches,and machines,which have been reviewed in several reports. Simultaneously,they also have been rapidly permeated and applied to the field of chemical and biological analysis as photoswitchable molecular probes and sensory chips,playing an increasingly significant role. So,it is worth emphasizing to review and summarize the last developments in the later topics as title of this paper. More than 100 relevant literatures are cited here and the prospects are pointed out.

关 键 词：偶氮苯衍生物 分子探针 传感芯片 生物分析 光开关 分子识别 综述 

分 类 号：O621.1[理学—有机化学]