Preparation of a new anion exchanger by pre-irradiation grafting technique and its adsorptive removal of rhenium(Ⅶ) as analogue to ^(99)Tc  

作　　者：俎建华 韦悦周 叶茂松 唐方东 何林锋 刘瑞芹 

机构地区：[1]School of Nuclear Science and Engineering, Shanghai Jiao Tong University [2]Shanghai Institute of Measurement and Testing Technology

出　　处：《Nuclear Science and Techniques》2015年第1期65-71,共7页核技术（英文）

基　　金：Supported by the National Natural Science Foundation of China(No.91226111 and 11305102);Shanghai Science and Technology Foundation(No.12DZ2293800)

摘　　要：A new anion exchanger with pyridine groups was prepared by grafting of 2-vinyl pyridine onto polypropylene(PP) nonwoven fabrics by pre-irradiation grafting technique, followed by quaternization of pyridine rings in grafted chains in reaction with bromoethane. The results showed that the grafting yield increased with the monomer concentration and conversion ratio of quaternization increased with the time. The grafted and quaternized fabrics were characterized by FT-IR, DSC, SEM and ICP. The possibility of adsorption of perrhenate(ReO–4), a nonradioactive analogue to pertechnetate(99TcO–4), from aqueous solution by anion exchanger was investigated. The experiments performed at pH= 0.1–6 showed that p H = 2.2 was the optimal acidity for ReO–4adsorption, and an adsorption equilibrium was achieved in 30 min. The reaction enthalpy was-12.55 k J/mol,indicating that the adsorption process is exothermic. XPS tests indicated that the Re O–4uptake was a typical ion exchange between Cl–on anion exchanger and ReO–4.A new anion exchanger with pyridine groups was prepared by grafting of 2-vinyl pyridine onto polypropy- lene （PP） nonwoven fabrics by pre-irradiation grafting technique, followed by quaternization of pyridine rings in grafted chains in reaction with bromoethane. The results showed that the grafting yield increased with the monomer concentration and conversion ratio of quaternization increased with the time. The grafted and quaternized fabrics were characterized by FT-IR, DSC, SEM and ICE The possibility of adsorption of perrhenate （ReO4）, a nonradioactive analogue to pertechnetate （99TCO4）, from aqueous solution by anion exchanger was investigated. The experiments performed at pH= 0.1-6 showed that pH = 2.2 was the optimal acidity for ReO4 adsorption, and an adsorption equilibrium was achieved in 30 min. The reaction enthalpy was -12.55 kJ/mol, indicating that the adsorption process is exothermic. XPS tests indicated that the ReO4- uptake was a typical ion exchange between Cl- on anion exchanger and ReO4-.

关 键 词：阴离子交换剂 吸附去除 接枝法 预辐照 制备 2-乙烯基吡啶 非织造织物 模拟 

分 类 号：TQ028.33[化学工程] O614.712[理学—无机化学]