微波萃取-GC/MS-MS测定乙二醇醚类有机溶剂  

Determination of residual glycol ethers in textiles by GC/MS-MS coupled with microwave extraction

作　　者：王成云[1] 张其芳[1] 林君峰[1] 沈雅蕾[1] 谢堂堂[1] 褚乃清[1] 

机构地区：[1]深圳出入境检验检疫局工业品检测技术中心,广东深圳518067

出　　处：《印染》2015年第6期46-49,共4页China Dyeing and Finishing

基　　金：国家质检总局科研项目(2012IK119);国家认监委科研制标项目(2012B402)

摘　　要：建立了气相色谱／串联质谱方法，测定纺织品中残留的15种乙二醇醚类有机溶剂。该方法以乙醇为萃取溶剂，100℃下微波萃取纺织品中残留的乙二醇醚类有机溶剂，萃取液直接进行气相色谱／串联质谱分析，外标法定量。在信噪比（S／N）为10的条件下，各组分的定量下限为5—20mg／kg。在三个加标水平下，平均回收率为81．7％-94．5％，相对标准偏差为2．1％-6．8％。该方法简单快速，可满足纺织品中乙二醇醚类有机溶剂残留量检测的技术要求。An effective method is established to simultaneously determine the residual contents of 15 glycol ethers in textiles. Residual glycol ethers in textiles are microwave-assisted extracted at 100 ℃, using ethanol as the extraction solvent. The extracts are then analyzed by gas chromatography/tandem mass spectrometry. The concentration of each analyte is calibrated by external standard method. The limits of quantification vary from 5～20 mg/kg at the condition of S/N of 10. The spiked average recoveries change from 81.7% to 94.5% under three different spiked levels while the relative standard deviation （RSD） varies from 2.1% ～ 6.8%. The proposed method is simple, rapid, accurate and sensitive. It can meet the technical demands of the determination of glycol ethers in textiles.

关 键 词：测试 乙二醇醚 微波辅助萃取 气相色谱法 串联质谱法 纺织品 

分 类 号：O657.63[理学—分析化学] TS107[理学—化学]