酯交换法合成水杨酸苄酯  

Synthesis of benzyl salicylate

作　　者：李成果 李娟 王迎宾 任再杰 陈银霞 马军 

机构地区：[1]河北诚信有限责任公司,河北石家庄051130

出　　处：《精细与专用化学品》2014年第10期39-41,共3页Fine and Specialty Chemicals

摘　　要：以水杨酸甲酯、苯甲醇为原料,在催化剂二丁基氧化锡催化下酯交换得到水杨酸苄酯。适宜的反应条件为:催化剂量为反应物总质量0.3%,n(水杨酸甲酯)∶n(苯甲醇)=1.0∶1.2,反应温度为130℃,反应时间为12h,在此条件下,水杨酸苄酯的总收率达97.6%。By using methyl salicytate and benzyl alcohol as raw materials, with dibutyltin oxide as catalyst, ben zyl salicylate was synthesized through interesterification. The optimal conditions were as follows., n（methyl salicy late） ＂ n（benzyl alcohol）=1. 0 .＂ 1.2, reaction temperature is 130℃, reaction time is 12h. Under the above condi tions, the yield of benzyl salicylate was 97.6%.

关 键 词：水杨酸甲酯 苯甲醇 水杨酸苄酯 酯交换 

分 类 号：TQ655[化学工程—精细化工]