Syntheses, Structures, and Luminescent Properties of Two ZnⅡ-organic Polymers Based on [Zn（ox）]n Chains and Different Imidazole Linkers  

作　　者：李斌 范黎明 宋维阔 刘新征 张修堂 

机构地区：[1]Advanced Material Institute of Research, College of Chemistry and Chemical Engineering, Qilu Normal University [2]State Key Laboratory of Crystal Materials, Shandong University

出　　处：《Chinese Journal of Structural Chemistry》2014年第9期1311-1318,共8页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China(20873150);the Natural Science Foundation of Shandong Province(ZR2010BL012,ZR2010BQ023)

摘　　要：Hydrothermal reactions of two imidazole derivatives （1,3,5-tib = 1,3,5-tris（1H- imidazol- 1 -yl）benzene, 1,4-bimb = 1,4-bis（1 H-imidazol- 1 -ylmethyl）benzene） and the ZnⅡ cations in the presence of oxalic acid （H2ox） afford two coordination polymers, namely, {[Zn（ox）（1,3,5- tib）]·2（H20）}n （1） and [Znl.5（OX）1.5（1,4-bimb）l.5]n （2）. Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, and powder X-ray diffraction （PXRD） analyses. Both complexes 1 and 2 are based on the 1D zigzag [Zn（ox）]n chains, and their final structures are controlled by the two different imidazole linkers, which expanded the structure along different directions, finally giving a 3D dia net for 1 and a 2D sql layer for 2. Moreover, the luminescent properties of 1 and 2 have been investigated.Hydrothermal reactions of two imidazole derivatives （1,3,5-tib = 1,3,5-tris（1H- imidazol- 1 -yl）benzene, 1,4-bimb = 1,4-bis（1 H-imidazol- 1 -ylmethyl）benzene） and the ZnⅡ cations in the presence of oxalic acid （H2ox） afford two coordination polymers, namely, {[Zn（ox）（1,3,5- tib）]·2（H20）}n （1） and [Znl.5（OX）1.5（1,4-bimb）l.5]n （2）. Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, and powder X-ray diffraction （PXRD） analyses. Both complexes 1 and 2 are based on the 1D zigzag [Zn（ox）]n chains, and their final structures are controlled by the two different imidazole linkers, which expanded the structure along different directions, finally giving a 3D dia net for 1 and a 2D sql layer for 2. Moreover, the luminescent properties of 1 and 2 have been investigated.

关 键 词：zinc 1 3 5-tris（1H-imidazol-l-yl）benzene 1 4-bis（1H-imidazol-l-ylmethyl）benzene oxalic acid luminescence property 

分 类 号：O631.1[理学—高分子化学]