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出 处:《Chinese Physics Letters》2015年第4期81-84,共4页中国物理快报(英文版)
基 金:Supported by the Key Basic Research Project of Hebei Province under Grant No 12963930D;the Natural Science Foundation of Hebei Province under Grant No F2013201250;the Science and Technology Research Projects of the Educational Department of Hebei Province under Grant No ZH2012030
摘 要:Silicon oxide films containing nanocrystalline silicon (nc-SiOx:H) are deposited by co-sputtering technology at low temperatures (〈400℃) that are much lower than the typical growth temperature of nc-Si in SiO2. The microstructures and bonding properties are characterized by Raman and ETIR. It is proven that an optimum range of su bstrate temperatures for the deposition of nc-SiOx :H films is 200-400℃, in which the ratio of transition crystalline silicon decreases, the crystalline fraction is higher, and the hydrogen content is lower. The underlying mechanism is explained by a competitive process between nc-Si Wolmer-Weber growth and oxidation reaction, both of which achieve a balance in the range of 200-400℃. We further implement this technique in the fabrication of multilayered nc-SiO=:H/a-SiOx:H films, which exhibit controllable nc-Si sizes with high crystallization quality.Silicon oxide films containing nanocrystalline silicon (nc-SiOx:H) are deposited by co-sputtering technology at low temperatures (〈400℃) that are much lower than the typical growth temperature of nc-Si in SiO2. The microstructures and bonding properties are characterized by Raman and ETIR. It is proven that an optimum range of su bstrate temperatures for the deposition of nc-SiOx :H films is 200-400℃, in which the ratio of transition crystalline silicon decreases, the crystalline fraction is higher, and the hydrogen content is lower. The underlying mechanism is explained by a competitive process between nc-Si Wolmer-Weber growth and oxidation reaction, both of which achieve a balance in the range of 200-400℃. We further implement this technique in the fabrication of multilayered nc-SiO=:H/a-SiOx:H films, which exhibit controllable nc-Si sizes with high crystallization quality.
关 键 词:SiO Using Magnetron Sputtering Low-Temperature Deposition of nc-SiO_x:H below 400
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