Selective hydrogenation of unprotected indole to indoline over N-doped carbon supported palladium catalyst  

作　　者：Dong-Shun Deng Guo-Qiang Han Xiao Zhu Xuan Xu Yu-Tong Gong Yong Wang 

机构地区：[1]Zhejiang Province Key Laboratory of Biofuel,College of Chemical Engineering,Zhejiang University of Technology [2]School of Chemistry and Chemical Engineering,Qufu Normal University [3]Key Lab of Applied Chemistry of Zhejiang Province,Department of Chemistry,Zhejiang University

出　　处：《Chinese Chemical Letters》2015年第3期277-281,共5页中国化学快报（英文版）

基　　金：support from the Joint Petroleum and Petrochemical Funds of the National Natural Science Foundation of China;China National Petroleum Corporation (No.U1162124);the Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China (No.LR13B030001);the Specialized Research Fund for the Doctoral Program of Higher Education (No.J20130060);the National Natural Science Foundation of China (No.21206085);Excellent Middle-aged and Young Scientists Research Award Foundation of Shandong Province (No.BS2011CL023);the Fundamental Research Funds for the Central Universities,the Program for Zhejiang Leading Team of S&T Innovation,and the Partner Group Program of Zhejiang University and the Max-Planck Society are greatly appreciated

摘　　要：Mesoporous N-doped carbon supported palladium catalyst Pd@CN0.132 was able to efficiently catalyze unprotected indole to indoline under mild conditions.In the aqueous system,a selectivity of 100% and conversion of 96% was achieved under 313 K and atmospheric hydrogen gas.Mesoporous N-doped carbon supported palladium catalyst Pd@CN0.132 was able to efficiently catalyze unprotected indole to indoline under mild conditions.In the aqueous system,a selectivity of 100% and conversion of 96% was achieved under 313 K and atmospheric hydrogen gas.

关 键 词：hydrogenation palladium indole selectivity catalyze heterogeneous simplicity entries molar recycle 

分 类 号：O626[理学—有机化学]