A novel synthesis of nitroform by the nitrolysis of cucurbituril  

作　　者：Hong-Yan Lu Jia-Rong Li De-Li Yang Qi Zhang Da-Xin Shi 

机构地区：[1]Chemical Engineering and Environment,Beijing Institute of Technology

出　　处：《Chinese Chemical Letters》2015年第3期365-368,共4页中国化学快报（英文版）

基　　金：supported by the grant of Beijing Institute of Technology

摘　　要：Cucurbituril has a high symmetry and rigid structure.When cucurbit[6]uril（CB[6]） was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid,nitroform（NF） was generated.NF also can be obtained by the nitration of both CB[5,7,8].This nitration procedure provides a lower risk,inexpensive,new preparation of nitroform,and the reaction condition of this new method is very mild.Cucurbituril has a high symmetry and rigid structure.When cucurbit[6]uril（CB[6]） was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid,nitroform（NF） was generated.NF also can be obtained by the nitration of both CB[5,7,8].This nitration procedure provides a lower risk,inexpensive,new preparation of nitroform,and the reaction condition of this new method is very mild.

关 键 词：anhydride inexpensive acetic symmetry rigid oligomer supramolecular hexane condensation solubility 

分 类 号：TQ560.1[化学工程—炸药化工]