新型N^C^N型铂(Ⅱ)配合物的合成  

Synthesis of A Novel NCN-Pincer Platinum(Ⅱ) Complex

作　　者：宁如光 肖朵朵[1] 汤伟佳[1] 殷江辉 于秋影[1] 向芸颉[1] 张灯青[1] 李贤英[1] 金武松[1] 

机构地区：[1]东华大学化学化工与生物工程学院,上海201620

出　　处：《广州化工》2015年第6期108-109,共2页GuangZhou Chemical Industry

摘　　要：在化学与材料科学研究领域中,有机功能性材料由于具有独特的电子结构和优良的光电活性而受到广泛地关注。其中,铂(II)配合物因其具有发光效率高、发光波长可调、发光寿命长等特点,在发光材料领域具有广泛的应用前景。在这里,以化合物1,3-二溴苯为原料,通过Suzuki偶联,金属配位等反应成功合成了一种新型N^C^N三齿铂(II)配合物(3)。该配合物经MALDI-TOF-MS得到确认。In the field of chemistry and materials science, organic functional materials have attracted widely attentions due to their unique electronic structure and excellent photoelectric activity.Among all of it, Pt（ II） complexes are widely used in the fields of luminescent materials because of their high luminescent efficiency, tunable emission wavelength and long lifetime.An novel NCN pincer platinum（ II） complex was successfully prepared by Suzuki coupling reaction and metal coordination reaction from compound 1 , 3-dibromobenzene.The structure was characterized by MALDI-TOF-MS.

关 键 词：铂(Ⅱ)配合物 SUZUKI偶联 金属配位 合成 

分 类 号：O327.8[理学—一般力学与力学基础]