溶剂抽提物对尾巨桉热变色的影响及光谱分析  

Effect of Extractives on Color Changes of Eucalyptus urophylla × Eucalyptus grandis and Its Spectrum Analysis

作　　者：高姗[1] 陈瑶[1] 高建民[1] 

机构地区：[1]北京林业大学,北京100083

出　　处：《东北林业大学学报》2015年第4期73-76,共4页Journal of Northeast Forestry University

基　　金：国家自然科学基金项目(31070490)

摘　　要：为探讨溶剂抽提物对尾巨桉热变色的影响,在过热蒸气条件下对抽提物进行热处理,之后采用冷水、热水、乙醇、甲醇、丙酮、正己烷等6种溶剂对热处理前后的尾巨桉木粉进行抽提,对热处理前后经过抽提的木粉进行色度指数的测定和红外光谱分析,并对抽提物进行紫外光谱分析。结果表明:1极性溶剂抽提物对尾巨桉颜色及其热处理后颜色变化影响较大,其中热水抽提物对颜色的影响最显著;2抽提物热处理后共轭结构增加,共轭体系能量降低,吸收带延伸至可见光范围,是木材受热后颜色加深的重要原因;3热处理后,尾巨桉木粉ΔL*为负值,即颜色变深,木材颜色均匀美观,可提高利用价值。Overheating steam treatment can darken the color of Eucalyptus urophylla × Eucalyptus grandis wood and make it look like precious wood,which can improve its utility value. For studying the effect of overheating steam treatment on discoloration of Eucalyptus urophylla × Eucalyptus grandis wood,we extracted the wood powder before and after heating treatment with cold water,hot water,alcohol,methyl alcohol,and acetone and n-hexane,and measured the color parameters of the samples before and after extracted. We used ultraviolet absorption spectrum and the FTIR spectra to evaluate chemical changes of extractives and wood powder. Polar solvents extract was more effective on color and color changes of E. grandis wood powder after heat treatment. Hot water extraction had the most important influence on wood color. The important reasons of color deepen after heat treatment were： after heat treatment,the conjugated structures of extractives increased,and the energy of conjugated system decreased,and the absorption band extended to the visible light range. After heat treatment,ΔL＊value of E. urophylla × E. grandis wood powder was negative,which meant the color was deepen,and the color of wood was uniform and beautiful with high utility value.

关 键 词：溶剂抽提物 尾巨桉 热变色 过热蒸汽处理 

分 类 号：TS193.21[轻工技术与工程—纺织化学与染整工程]