纳米四氧化三铁／天然橡胶复合材料的制备及性能研究  

Preparation and property of Fe_3O_4 nanoparticles/natural rubber composites

作　　者：袁吉龙[1] 毛敏敏[1] 曹阳[1] 王江[1] 

机构地区：[1]海南大学材料与化工学院,海南特有资源与优势化工材料教育部重点实验室,海口570228

出　　处：《化工新型材料》2015年第4期33-36,共4页New Chemical Materials

基　　金：国家自然科学基金项目(51361009);海南省重点科技计划项目(ZDXM20120066);海南省自然科学基金(511106)

摘　　要：采用化学共沉淀法经过硅烷偶联剂改性制备纳米四氧化三铁粒子(纳米Fe3O4),再通过不同的制备工艺与天然胶乳(NR)共混,制备纳米Fe3O4/天然橡胶复合材料(纳米Fe3O4/NR)。利用马尔文MS2000激光粒度仪、X射线衍射仪(XRD)和扫描电子显微镜(SEM)等分析仪器分别对所制备样品的形貌、成分及结构进行表征。结果表明:化学共沉淀法制备的纳米Fe3O4粒子为结晶态,粒径约为47nm。硅烷偶联剂可有效地对纳米Fe3O4表面进行改性;改性后的纳米Fe3O4粒子,增强了纳米Fe3O4/NR复合材料的界面作用,提高了纳米Fe3O4粒子在NR中的分散性,改善了复合材料的结构和性能。Fe3O4 nanoparticles （nano-F3O4 ）, which was blend with natural rubber latex with the help of various preparation technology to prepare nano-Fe3O4/natural rubber composites （nano-Fe3O4/NR）, was modified by the silane coupling agent through the chemical co-precipitation method. The morphology, structure and composition of the samples were characterized by Malven Laser Mastersizer 2000 Particle Size Analyzer,X-ray powder diffraction （XRD）, scanning e- lectron microscope （SEM） and the other analytical instruments, respectively. The results demonstrated that nanoparticles were crystal state and the average size of the particles was about 47nm. The surface of nanoparticles could be effectively modified by silane coupling agent. The interfacial interaction and the dispersion of the composites was enhanced, result to improve the structure and the mechanical properties of the composites with the incorporation of nanoDarticles.

关 键 词：纳米FE3O4 天然橡胶 硅烷偶联剂 改性 复合材料 

分 类 号：TQ332[化学工程—橡胶工业] TB33[一般工业技术—材料科学与工程]