三氯异氰尿酸促进硫代磷酸酯的高效简便合成  

Trichloroisocyanuric Acid-Promoting the Convenient and Efficient Synthesis of Thiophosphates

作　　者：王亮[1] 陈群[1] 何明阳[1] 

机构地区：[1]常州大学石油化工学院,江苏常州213164

出　　处：《常州大学学报（自然科学版）》2015年第2期6-10,共5页Journal of Changzhou University：Natural Science Edition

基　　金：国家自然科学基金项目资助(21302014)

摘　　要：以三氯异氰尿酸(TCCA)为促进剂,硫酚和亚磷酸酯为原料合成一系列硫代磷酸酯,并用1 H NMR,13 C NMR和质谱对产物结构进行表征。与传统方法相比,该法快速、高效、反应条件温和且底物兼容性好,为硫代磷酸酯的合成提供新的途径。A series of thiophosphates were synthesized by coupling reaction between thiophenols and phos-phites promoted by trichloroisocyanuric acid（TCCA）. All the compounds were characterized by 1H NMR, 13C NMR and Mass. Compared with conventional methods, this protocol shows some advantages such as fast, highly efficient, mild and good substrate compatibility. This work provides a new methodology for the synthesis of thiophosphates.

关 键 词：三氯异氰尿酸 硫代磷酸酯 磷酸酯 硫酚 

分 类 号：O621.3[理学—有机化学]